| 引用本文： |
-
韦新红,陈永欣,黎香荣,谢毓群.微波消解-等离子体原子发射光谱法测定3种铅锌矿物中的10种组分[J].广西科学院学报,2012,28(3):194-196. [点击复制]
- WEI Xin-hong,CHEN Yong-xin,LI Xiang-rong,XIE Yu-qun.Determination of 10 Components in Lead Ore,Lead Concentrates and Lead-zinc Ore Using Inductively Coupled Plasma Atomic Emission Spectrometry and Microwave-assisted Digestion[J].Journal of Guangxi Academy of Sciences,2012,28(3):194-196. [点击复制]
|
|
| 摘要: |
| 铅矿、铅精矿、铅锌矿经混合酸(HCl+HNO3+HF)在高压密闭容器中微波消解后,通过电感耦合等离子体发射光谱法测定样品中的Zn、CaO、Na2O、MnO、MgO、As、Cu、Cd、Al2O3、K2O共10种组分。最佳仪器工作条件为:功率1.3 kW,等离子体气流量15 ml/min,辅助气流量0.2 ml/min,样品提升量1.5 ml/min。各元素相关系数均大于0.9991,回收率91.3%~109.7%。 |
| 关键词: 铅矿 铅精矿 铅锌矿 微波消解 电感耦合等离子体发射光谱法 |
| DOI： |
| 投稿时间：2012-02-01修订日期：2012-04-26 |
| 基金项目: |
|
| Determination of 10 Components in Lead Ore,Lead Concentrates and Lead-zinc Ore Using Inductively Coupled Plasma Atomic Emission Spectrometry and Microwave-assisted Digestion |
|
WEI Xin-hong, CHEN Yong-xin, LI Xiang-rong, XIE Yu-qun
|
| (Fangchenggang Entry-Exit Inspection and Quarantine Bureau, Fangchenggang, Guangxi, 538001, China) |
| Abstract: |
| Lead ore,lead concentrates and lead-zinc ore were prepared by microwave assisted digestion in a pressurized vessel mixed with HCl,HNO3 and HF.Ten components in sample solution including zinc,calcium oxide,sodium,hydroxide,manganese oxide,magnesiumoxide,arsenic,copper,cadmium,alumina and potassium hydroxide were determined by inductively coupled plasma atomic emission spectrometry (ICP-AES).The optimum working conditions of the instrument was obtained.The powder was 1.3 kW.The plasma gas flow rate was 15 mL/min.The auxiliary gas flow rate was 0.2 mL/min.The sample uptake amount was 1.5 mL/min.The correlation coefficient of all elements was over 0.9991 and the recovery rate was 91.3%~109.7%. |
| Key words: lead ore lead concentrates lead-zinc ore microwave assisted digestion inductively coupled plasma atomic emission spectrometry |
