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林润国,吕昆明,林叶新,何裕东,何通海.22种含氮农药分子中的基团个数与其高效液相色谱相对响应值的关系研究[J].广西科学院学报,2010,26(3):335-337,342. [点击复制]
- LIN Run-guo,LV Kun-ming,LIN Ye-xin,HE Yu-dong,HE Tong-hai.Study on the Relationship between the Numbers of Functional Groups in 22 Nitrogen-Containning Pesticides and Their Relative Response Value of High Performance Liquid Chromatography[J].Journal of Guangxi Academy of Sciences,2010,26(3):335-337,342. [点击复制]
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| 22种含氮农药分子中的基团个数与其高效液相色谱相对响应值的关系研究 |
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林润国1,2, 吕昆明3, 林叶新4, 何裕东5, 何通海5
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| (1.广西民族师范学院, 广西崇左 532200;2.广西化工研究院, 广西南宁 530001;3.广西乐土生物科技有限公司, 广西南宁 530000;4.重庆大学, 四川重庆 400030;5.广西田园生化股份有限公司, 广西南宁 530007) |
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| 摘要: |
| 使用ODS-C18(5μm)为固定相的150mm×4.6 mm(i.d.)的不锈钢柱,甲醇-水流动相,进行22种氯基酸酯类和酰胺类农药(速灭威、异丙威、多菌灵、霜脲氰、仲丁威、敌稗、克百威、抗蚜威、禾草丹、甲草胺、乙草胺、恶霜灵、甲霜灵、异丙甲草胺、腐霉利、苯菌灵、丁草胺、异菌脲、甲基硫菌灵、哒螨灵、咪鲜胺、吡嘧磺隆)的高效液相色谱测定。同时采用多元线性拟合法求出这些农药分子中16种基团的个数与其高效液相色谱相对响应值关系的回归方程,得到方程的计算值与实验测定值一致的结果。 |
| 关键词: 基团 分子 农药 酰胺 氨基酸酯 高效液相色谱 相对响应值 |
| DOI： |
| 投稿时间：2010-06-26修订日期：2010-08-10 |
| 基金项目: |
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| Study on the Relationship between the Numbers of Functional Groups in 22 Nitrogen-Containning Pesticides and Their Relative Response Value of High Performance Liquid Chromatography |
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LIN Run-guo1,2, LV Kun-ming3, LIN Ye-xin4, HE Yu-dong5, HE Tong-hai5
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| (1.Guangxi Normal University for Nationalities, Chongzuo, Guangxi, 532200, China;2.Guangxi Research Institute of Chemical Industry, Nanning, Guangxi, 530001, China;3.Guangxi LETU Limitied Company of Biology Science and Technology, Nanning, Guangxi, 530000, China;4.Chongqing University, Chongqing, Sichuan, 400030, China;5.Guangxi Tianyuan Biochemistry Co., Ltd, Nanning, Guangxi, 530007, China) |
| Abstract: |
| Tweenty-two carbamade and acyl amide pesticides(Metolcarb, isoprocarb, carbendazim, cymoxanil, fenobucarb, propanil, carbfuran, pirimicarb, thiobencarb, alachlor, acetochlor, oxadixyl, metalaxyl, metolachlo, butachlor, procymidone, benomyl, iprodione, thiophanate-methy, pyridaben, prochloraz, pyrazosulfuron) have been determinatied by high performance liquid chromafography(HPLC), using 150mm×4.6mm (i.d.) stainless steel column packed ODS-C18 stationary phase and methonal-wather mobil phase.Employed multiple linear regression,the recursive equation between relative response value and their numbers of functional groups in molecules was obtained.The caculation value consisted with experiment value. |
| Key words: functional groups molecule pesticides acyl amide carbamade high performance liquid chromatography (HPLC) relative response value |
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