| 引用本文： |
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崔建国,黄燕敏,曾陇梅.重铬酸吡啶盐作用下烯丙基甾醇的氧化反应研究[J].广西科学,2001,8(4):281-283. [点击复制]
- Cui Jianguo,Huang Yanmin,Zeng Longmei.Novel Oxidation of Homoallylic Sterols with Pyridinium Dichromate[J].Guangxi Sciences,2001,8(4):281-283. [点击复制]
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| 摘要: |
| 在不同的反应条件下,用重铬酸吡啶盐(PDC)氧化豆甾醇,分别得到以豆甾-4,22-二烯-6β-羟基-3-酮或豆甾-4,22-二烯-3,6-二酮为主的产物。结果与有关文献的报道有所不同。 |
| 关键词: 烯丙基甾醇 重铬酸吡啶盐(PDC) 豆甾-4,22-二烯-6β-羟基-3-酮 豆甾-4,22-二烯-3,6-二酮 |
| DOI： |
| 投稿时间：2001-06-07修订日期：2001-08-13 |
| 基金项目:广东省自然科学基金(970154)资助。 |
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| Novel Oxidation of Homoallylic Sterols with Pyridinium Dichromate |
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Cui Jianguo, Huang Yanmin, Zeng Longmei
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| (Dept of Chem, Guangxi Teachers College, East Mingxiulu, Nanning, Guangxi, 530001, China) |
| Abstract: |
| Stigmasterol was oxidized with pyridinium dichromate Stigmast-4,22-dien-6β-ol-3 one and stigmast-4,22-dien-3,6-dione were obtained as main product separately in different reactive conditions. The result was different from the report in the related literature. |
| Key words: homoallylic sterols pyridinium dichromate (PDC) stigmast-4,22-dien-6β-ol-3 one stigmast-4,22-dien-3,6-dione |
