| 引用本文： |
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王修建,梁宏,曾建强,翟应离,王秋莹.聚合钼邻巯基苯酚配合物的合成及性质[J].广西科学,1995,2(1):28-29,33. [点击复制]
- Wang Xiujian,Liang Hong,Zeng Jianqiang,Zhai Yingli,Wang Qiuying.Synthesis and Spectroscopic Properties of Polymolybdenum o-mercaptophenol Complex[J].Guangxi Sciences,1995,2(1):28-29,33. [点击复制]
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| 摘要: |
| 以(n-Bu4N)4[Mo8O26]为原料,邻巯基苯酚为配体,在乙腈中合成了混合价聚合钼配合物(n-Bu4N)4[Mo5O10(S-O)4(HS-O)2].通过元素分析、红外光谱、1HNMR谱、电子光谱、ESP谱、差热-热重分析。对此配合物进行了表征,并提出可能结构。 |
| 关键词: 聚合钼配合物 钼硫键 邻巯基苯酚 |
| DOI： |
| 投稿时间：1994-04-08修订日期：1994-08-03 |
| 基金项目: |
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| Synthesis and Spectroscopic Properties of Polymolybdenum o-mercaptophenol Complex |
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Wang Xiujian, Liang Hong, Zeng Jianqiang, Zhai Yingli, Wang Qiuying
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| (Department of chemistry, Guangxi Normal University, Sanlidian, Guilin, Guangxi, 541004) |
| Abstract: |
| The polymolybdenum complex (n-Bu4N)4[Mo5O10(S-O)4(HS-O)2] was synthe sized in acetonitrile with o-mercaptophenol as the ligand and (n-Bu4N)4[Mo8O26] as the parent. The properties of the complex were characterized by elemental analysis, molar conductivity, electronic spectra, infrared spectra, 1HNMR spectra and TG-DTA. The most possible structure was proposed on the basis of spectra data. |
| Key words: polymolybdenum complex molybdenum-sulfur bond o-mercaptophenol |
