| 引用本文： |
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梁春群,张丽霞.钐、铕-3-噻吩乙酸二元、三元配合物的合成及表征[J].广西科学,2012,19(1):64-68. [点击复制]
- LIANG Chun-qun,ZHANG Li-xia.Synthesis and Characterization of the Binary and Ternary Complexes of Rare Earth with 3-Thiopheneacetic acid and 1,10-Phenanthroline[J].Guangxi Sciences,2012,19(1):64-68. [点击复制]
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| 摘要: |
| 以3-噻吩乙酸为第一配体合成钐、铕的二元配合物,以3-噻吩乙酸为第一配体,phen为第二配体合成钐、铕的三元配合物,通过元素分析和EDTA滴定分析确定其通式为REY32H2O、REY3phen(RE=Eu,Sm;Th=3-噻吩乙酸根,phen=邻菲啰啉)后,测定4种配合物的红外光谱、紫外光谱和荧光光谱及TG-DTG曲线。结果表明,由于第二配体的加入,对稀土离子的发光起到了敏化作用,增强了稀土离子的发光强度,并且三元配合物热稳定性比二元配合物的热稳定性好。 |
| 关键词: Sm3+ Eu3+ 3-噻吩乙酸 1,10-邻菲啰啉 发光性质 |
| DOI： |
| 投稿时间：2011-09-07修订日期：2012-01-13 |
| 基金项目:广西教育厅基金项目(201010LX306)和广西师范学院基础研究基金项目(0710A001)资助。 |
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| Synthesis and Characterization of the Binary and Ternary Complexes of Rare Earth with 3-Thiopheneacetic acid and 1,10-Phenanthroline |
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LIANG Chun-qun, ZHANG Li-xia
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| (College of Chemistry and Life Science, Guangxi Teachers Education University, Nanning, Guangxi, 530001, China) |
| Abstract: |
| Four solid complexes of rare earth with 3-thiopheneacetic acid and 1, 10-phenanthroline were synthesized, and the general formula of these complexes was proved to be REY32H2O and REY3 phen (RE=Eu,Sm;Th=3-Thiopheneacetic acid,phen=Phenanthroline)by element analyse and titration analyse.These complexes were characterized by IR spectroscopy,UV-spectroscopy,Fluorescent spectrum and TG-DTG.The results showed that RETh3 phen had better thermal stability than REY32H2O, and that adding the second ligand could enhance Eu3+ or Sm3+ ion fluorescence intensity. |
| Key words: Europium(Ⅲ) samarium(Ⅲ) 3-thiopheneacetic acid 1,10-phenanthroline luminescence properties |
