| 引用本文： |
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银秀菊,蒋毅民,刘旭辉.[Cu(HDPC)2]3·(HOx)2·6.5H2O的合成及晶体结构[J].广西科学,2007,14(3):270-273. [点击复制]
- YIN Xiu-ju,JIANG Yi-min,LIU Xu-hui.Synthesis and Crystal Structure of[Cu (HDPC)2]3· (HOx)2·6.5H2O[J].Guangxi Sciences,2007,14(3):270-273. [点击复制]
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| 摘要: |
| 在水溶液中首次合成配合物[Cu(HDPC)2]3·(HOx)2·6.5H2O(化学式为C60H51Cu3N8O32.50),并对其结构用X-射线衍射和元素分析表征。配合物属三斜晶系,P-1空间群,晶胞参数a=14.702(3),b=16.056(2)Å,c=16.137(3)Å;α=113.951(9)°,β=107.996(13)°,γ=97.154(11)°,v=3171.0(9)Å3,Z=2,Dc=1.670M g/m3,μ=1.102mm-1。铜在晶体结构中均为压扁的八面体构型。 |
| 关键词: 配合物 铜 吡啶-2,6-二甲酸根 晶体结构 |
| DOI： |
| 投稿时间：2007-04-18 |
| 基金项目:广西自然科学基金项目(No.0339034);广西高校重点建设实验室(桂西北特色资源研究与开发实验室)资助 |
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| Synthesis and Crystal Structure of[Cu (HDPC)2]3· (HOx)2·6.5H2O |
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YIN Xiu-ju1, JIANG Yi-min2, LIU Xu-hui1
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| (1.Department of Chemistry & Biology, Hechi College, Yizhou, Guangxi, 546300, China;2.College of Chemistry & Chemical Engineering, Guangxi Normal University, Guilin, Guangxi, 541004, China) |
| Abstract: |
| The complex formulated[Cu (HDPC)2]3· (HOx)2·6.5H2O (HDPC- is pyridine-2, 6-dicarboxylate, Hox is 8-Hydroxyquindine) has been synthesized in the solution.Its chemical formula is C60H51Cu3N8O32.50.The crystal structure was determined by X-ray diffraction.The crystal structure of the complex belongs to triclinic system with space group P-1, a=14.702 (3)Å, b=16.056 (2)Å, c=16.137 (3)Å;α=113.951 (9)°, β=107.996 (13)°, γ=97.154 (11)°, v=3171.0 (9)Å3, Z=2, Dc=1.670Mg/m3, μ=1.102mm-1.In the crystal, Cu (Ⅱ) ion is a distorted octahedron with six-coordinated. |
| Key words: complex copper pyridine-2,6-dicarboxylate crystal structure |
