| 引用本文： |
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刘旭红,蒋治良,覃诚真.Rh（Ⅲ）-KIO4-亮绿催化新体系的极谱研究及应用[J].广西科学,1995,2(2):24-27. [点击复制]
- Liu Xuhong,Jiang Zhiliang,Qin Chenzheng.Polarographic Study on the New Catalytic System of Rh(Ⅲ)-KIO4-Brilliant Green and Its Appplication[J].Guangxi Sciences,1995,2(2):24-27. [点击复制]
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| 摘要: |
| 在pH3.8HOAc-NaOAc缓冲溶液中及100℃加热条件下,Rh(Ⅲ)强烈催化KIO4氧化亮绿褪色。亮绿于-0.60V处产生一灵敏的导数极谱波。据此,本文采用线性扫描导数示波极谱研究了这一新的指示反应,建立了一个检出限和测定范围分别为3.0×10-5μg/mL和6×10-5~2.0×10-3μg/mL铑的催化分析新方法,并用于试样分析。 |
| 关键词: 铑 亮绿 催化法 示波极谱法 |
| DOI： |
| 投稿时间：1994-11-28 |
| 基金项目:国家自然科学基金和广西青年自然科学基金 |
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| Polarographic Study on the New Catalytic System of Rh(Ⅲ)-KIO4-Brilliant Green and Its Appplication |
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Liu Xuhong, Jiang Zhiliang, Qin Chenzheng
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| (Guangxi Normal University, Sanlidian, Guilin, Guangxi, 541004) |
| Abstract: |
| Under the conditions of pH3.8 acetate buffer solution at 100℃, Rh(Ⅲ) Strongly Catalyzed the redox reaction between brilliant green and KIO4, brilliant green exhibits a sensitl.e derivative Oscilloplarographic waye at-0.60 V vs. SCE. On these grounds, a novel and highly sensitive catalyticmethod for deteromination of Rh in the range of 0.06-2.0 μg/mL was proposed, with a detection limit of 0.03 μg/mL Rh. Rhodium in synthetic sample and catalyst analysed by this catalytic method showed excellent results. |
| Key words: Rhodium brilliant green Catalytic method Oscillopolarography |
